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Nitrogen and phosphorus cycles: Always recycle!

Video transcript
Brown hair: There's nothing quite so terrible as needing something that's sitting right in front of you, but not being able to get it. Like say you're on a life boat in the ocean and you're super thirsty and there's 300 million cubic miles of water sitting right in front of you, but you can't drink any of it. Or having to sit next to Megan Kale everyday in math class but knowing she's really dramatically out of your league. A lot of organisms on earth find themselves in this situation, pretty much constantly except that the thing that's everywhere that they can't have isn't water or physical closeness, it's nutrients, specifically nitrogen and phosphorus. Of course there are tons of elements that cycle around the earth, hanging out in one place or form for awhile before moving on to the next. As you know, living things need a bunch of stuff. Animals for instance need oxygen, and carbon and hydrogen. These elements basically cover the water cycle and the carbon cycle that I talked about last time, but we're also about 3% nitrogen and 1% phosphorus. Those numbers might not sound too significant, but even though we just got teensy bits of this stuff in our bodies we need nitrogen to make amino acids which make proteins which make our whole bodies up and DNA and RNA, too. DNA and RNA also require phosphorous, not to mention that phosphorous is the P in ATP and the phospho in phospholipid bilayer. We might need a ton of this stuff, but it is important and it's hanging out everywhere. The air we breath is mostly nitrogen and the water and rocks all around us are jam packed full of phosphorous. Like I said they're rarely in a form that's biologically available. As per usual, the organisms that solve this problem are the plants. Anything else that needs these nutrients are just going to have to eat some plants or eat something that ate the plants. But how do plants solve this problem and why is it a problem in the first place? Well, give me a few minutes, I'll explain. (upbeat music playing) Let's talk about the nitrogen cycle first since nitrogen really is actually all around us, like I can feel it right now, there it is, in the air. Why is it so hard to get this stuff that's constantly surrounding us in the air into our actual bodies to be useful for us? Because even though nitrogen gas makes up about 78% of the atmosphere, you'll notice here that nitrogen gas is made up of two nitrogen atoms stuck together with a triple bound. It's one thing to break apart a single covalent bond, but three? As you can imagine those two nitrogen atoms are a total pain to pry apart, but that molecule has to be split in order for a plant to get at the pieces. In fact, plants can assimilate a bunch of different forms of nitrogen, nitrates, nitrites to a lesser extent and even ammonium, which is what you get when you mix ammonia with water, but all that darn nitrogen gas in the atmosphere is beyond their powers of assimilation. So, plants need help taking advantage of this ocean of nitrogen that we're all swimming in, which is why they need to have that nitrogen fixed so that they can use it. Even though plants aren't wile enough to wrangle those two nitrogen atoms apart, certain nitrogen fixing bacteria are. These bacteria hang out in soil or water or even form symbiotic relationships with the root nodules of some plants, most of which are legumes. That's a pretty big family of plants, soybeans, clover, peanuts, kudzu, all legumes. These bacteria just sit around converting atmospheric nitrogen into ammonia, which then becomes ammonium when it's mixed with water which can be used by plants. They do this with a special enzyme called nitrogenase which is the only biological enzyme that can break that crazy triple bond. Ammonia can also be made by decomposers, fungi, protists; other kinds of bacteria that munch on your proteins and DNA after you die, but they're not picky they like poop and urine too. Then once this has happened, other bacteria known as nitrifying bacteria can take this ammonia and convert it into nitrates; three oxygen atoms attached to a single nitrate atom and nitrite; two oxygens attached to a nitrogen. Those are even easier than ammonium for plants to assimilate. So, the take home here is, if it wasn't for these bacteria there would be a whole lot less of biologically available nitrogen hanging around and as a result there would be a lot fewer living things on the planet. As usual, thanks bacteria we owe you one, but I should mention that it's not just bacteria who can wrangle those two nitrogen atoms apart, lightning of all things has enough energy to break bonds between nitrogens, which is obviously awesome and therefore worth mention. And in the 20th century, smarty pants humans also figured out various ways to synthetically fix a ton of nitrogen all at once, which is why we have synthetic fertilizers now, there's so much food growing all over the place. Once the atmospheric nitrogen is converted into a form that plants can use to make DNA and RNA and amino acids, organic nitrogen takes off up the food chain, animals eat the plants and use all that sweet, sweet, bio-available nitrogen to make our own amino acid. Then we pee or poop it out or die and the decomposers go to town on it, breaking it down into ammonia and it just keeps going, until one day, that organic nitrogen finds itself in denitrifying bacteria who's job it is to metabolize the nitrogen oxides and turn them back into nitrogen gas using a special enzyme called nitrate reductase. These guys do their business and then release the N2 back in the atmosphere. That my friends is the nitrogen cycle, if you remember nothing else remember that a) you owe bacteria a solid because they were smart enough to make an enzyme that could bust open the triple bonds of nitrogen gas, b) you owe plants a solid for wrestling nitrogen into their bodies so that you can just eat a carrot and not have to think about it and c) nitrogen is awesome and everywhere and yet also elusive and deserving of your respect. So, moving on to the phosphorous cycle. The interesting thing about phosphorous is that it's the only element that we're going to talk about that doesn't involve the atmosphere. Phosphorous wants nothing to do with your air, however, the lithosphere, a fancy word for the earth's crust is amply supplied with phosphorous. Rocks contain inorganic phosphates especially sedimentary rocks that originated in old ocean floors and lake beds where living things died and sank to the bottom where their phosphorous rich bodies piled up and made phosphorous rich rocks over time. Unfortunately, there aren't a lot of rock eating organisms on earth, just a couple of bacteria which are called lithotroph's, by the way. However, when these rocks are re-exposed and water erodes them some of the phosphates are dissolved into the water. These dissolved phosphates are immediately available to and assimilated by plants which are then eaten by animals. From here, the same thing goes for the decomposers as with the nitrogen cycle, when a leaf drops or something poops or dies, the decomposers break it down and release the phosphates back into the soil or water. Phosphates get about as much down time in the soil as a twenty dollar bill on the sidewalk. Decomposed phosphates is immediately re-assimilated back into plants and this little cycle just keeps going and going; plants, to the animal, to the decomposers, to the soil and back into a plant. That is until that atom of phosphorous makes its way into some kind of body of water, because aquatic and marine ecosystems need phosphorous like crazy. Once a phosphorous atom makes its way into a deep lake or ocean it cycles around among the organisms there, algae, plankton, fish, and this cycling can go on for a long time. I mean, not as long as a phosphorous atom trapped in a rock, that can be millions of years, but by some estimates a single phosphorous atom can be caught in a biological cycle for a hundred thousand years. Eventually it's in something that dies and falls into a hole so deep that decomposers can't survive there, then sedimentation builds up and turns into rock which are eventually uplifted into mountains and exposed and the phosphates are weathered back out and it's a cycle! So yeah, that's the deal with nitrogen and phosphorous, living things need them, but even though they're all over the place, they're at a premium in biological systems because they're hard to get at, either because they have to be converted into a form that organisms can use or they're locked away underground. But you know who the smartest monkey's are, us, and yeah, you can bet your face that we figured out how to unleash all kinds of nitrogen and phosphorous onto this big green planet. Mostly in an effort to help feed our children and each other, we usually mean well, but we can be a bit overbearing sometimes. It's just the human way, to see something in nature that seems to be lacking or imperfect and try to make it the best thing ever. So, with the phosphorous and nitrogen cycles we have introduced fertilizers, lots and lots of fertilizers. The main ingredients of which are, you guessed it, nitrogen and phosphorous. The story of how we learned to synthesize nitrogen into ammonia for fertilizers and chemical weapons is a very, very interesting one involving an evil lunatic. I suggest that as soon as this is over you watch this video on Fritz Haber, the guy who made all of this happen during World War I. You've heard of too much of a good thing, right? Well, through the miracle of synthetic fertilizer's we're able to grow much, much more food than we ever have before and as a result ecosystems all over the world are being bombarded by these incredible amounts of nitrogen and phosphorous. This takes us into the next chapter in our exploration of ecology, the human impacts on the biosphere. Sometimes out of our desire to make nature better, sometimes out of stupid human selfishness, and most often both, we've ended up really messing up the environment in more ways than we can count.