We've already seen alcohols in
many of these videos, but I thought it was about time
that I actually made a video on alcohols. Now, alcohols is the general
term for any molecule that fits the pattern some type of
functional group or chain of carbons OH. And they use the letter R. And I've used it before. R stands for radical. And I don't want you to confuse this R with free radical. It means completely
different things. R in this form really just means
a functional group or a chain of carbons here. It doesn't mean a
free radical. This just means it could be
just something attached to this OH right there. Now another point of
clarification, do not think that anything that fits this
pattern is drinkable. Do not associate it with the
traditional alcohol that you may or may not have
been exposed to. Traditional drinking alcohol
is actually ethanol. Alcohol is actually--
let me write out the molecular formula. CH3, CH2, and then OH. This is what is inside of wine
and beer and hard liquor, or whatever you might want. You do not want to drink and
maybe you might not actually want to drink this either, but
you definitely do not want to drink something like methanol. It might kill you. So you do not want to do
something like this. You do not want to
ingest that. Might kill or blind you. This might do it in a
more indirect way. So I want to get that out of
the way and just so that we get kind of a little bit more
comfortable with alcohols, and we've seen them involved
in other reactions. We've seen hydroxides act
as nucleophiles and Sn2 substitution reactions
create alcohols. But I want to do is just learn
to get comfortable and really make sure we know how to
name these things. So let's just name these
molecules that I drew right before I pressed record
right over here. So over here, like everything
else, we always want to define the longest carbon chain. We have 1, 2, 3, 4, 5 carbons. So it's going to be pent. And there's no double bonds. So it's a pentane. So I'll just write pentane
right then. And we're not going to just
write a pentane because actually, the fact that makes
it an alcohol, that takes precedence over the fact
that it is an alkane. So it actually, the suffix of
the word will involve the alcohol part. So it is pentanol. That tells us that's
an alcohol. And to know where the OH is
grouped, we'll start numbering closest to the OH. So 1, 2, 3, 4, 5. Sometimes it'll be called
2-pentanol. And this is pretty clear because
we only have one group here, only one OH. So we know that that is
what the 2 applies to. But a lot of times, if people
want to be a little bit more particular, they might
write pentan-2-ol. And this way is more useful,
especially if you have multiple functional groups. So you know exactly
where they sit. This one is harder to say. 2-pentanol is pretty
straightforward. Now let's try the name this
beast right over here. So we have a couple of
things going on. This is an alkyne. We have a triple bond. It's an alkyne. We have two bromo groups here. And it's also an alcohol. And alcohol takes precedence
on all of them. So we want to start numbering
closest to the alcohol. So we want to start numbering
from this end of the carbon chain. And we have 1, 2, 3, 4,
5, 6, 7, 8 carbons. We want to call it an octyne. But because we have an alcohol
there, we want to call this an octyne-- let me make
it very clear. So oct tells us that
we have 8 carbons. Now we have to specify where
that triple bond is. The triple bond is
on the 5 carbon. You always specify the lower
number of the carbons on that triple bond. So it is oct-5-yn. That tells us that's where
the triple bond is. And then we have the
OH on the 4 carbon. So 4-al. And now we have these
two bromo groups here on the 7 carbon. So it's 7,7-dibromo
oct-5-yn-4-al. And this would all
be one word. Let me make sure that
you realize that this should be connected. I just ran out of space. So that's probably about as
messy of a thing you'll have to name, but just showing
you that these things can be named. Now let's think about this
one over here in green. So we have 1, 2, 3,
4, 5, 6 carbons. So it's going to be a hex. And they're all single bonds,
so it's a hexane. It's a cyclohexane. But then of course, the
hydroxide or the hydroxy group I should call it,
takes dominance. It's a hexanol. So this is a cyclohexanol. And once again, that comes
from the OH right there. And you don't have
to number it. Because no matter what carbon
it's on, it's on the same one. If you had more than one of
these OH groups, then we would have to worry about
numbering them. Let's just do this one
right over here. So once again, what is
our carbon chain? We have 1, 2, 3 carbons. And we have the hydroxy
group attached to the 1 and the 3 carbon. Prop is our prefix. It is an alkane. So we would call this--
and there's a couple of ways to do this. We could call this 1 comma
3 propanediol. Actually, I don't have
to put a dash their. Propanediol. And over here, we would add the
E because we have the D right there. So it's propanediol. If it wasn't diol, it
would be propanal. You wouldn't have the E,
D and the I there. So this would specify we're at
the 1 and the 3 carbons. We have the hydroxy group. Or this could also be written
as propane- 1, 3- diol. And once again, the di is
telling us that we have two of the hydroxy groups attached
to this thing. But either of these things are
ways that you would see this molecule named.