Class 11 Chemistry (India)
- Bohr's model of hydrogen
- Absorption/emission lines
- Absorption and emission
- Emission spectrum of hydrogen
- Bohr model radii (derivation using physics)
- Bohr model radii
- Bohr model energy levels (derivation using physics)
- Bohr model energy levels
- Atomic Energy Levels
How Bohr's model of hydrogen explains atomic emission spectra
- Bohr's model of hydrogen is based on the nonclassical assumption that electrons travel in specific shells, or orbits, around the nucleus.
- Bohr's model calculated the following energies for an electron in the shell, :
- Bohr explained the hydrogen spectrum in terms of electrons absorbing and emitting photons to change energy levels, where the photon energy is
- Bohr's model does not work for systems with more than one electron.
The planetary model of the atom
At the beginning of the 20th century, a new field of study known as quantum mechanics emerged. One of the founders of this field was Danish physicist Niels Bohr, who was interested in explaining the discrete line spectrum observed when light was emitted by different elements. Bohr was also interested in the structure of the atom, which was a topic of much debate at the time. Numerous models of the atom had been postulated based on experimental results including the discovery of the electron by J. J. Thomson and the discovery of the nucleus by Ernest Rutherford. Bohr supported the planetary model, in which electrons revolved around a positively charged nucleus like the rings around Saturn—or alternatively, the planets around the sun.
Image of Saturn and rings
However, scientists still had many unanswered questions:
- Where are the electrons, and what are they doing?
- If the electrons are orbiting the nucleus, why don’t they fall into the nucleus as predicted by classical physics?
- How is the internal structure of the atom related to the discrete emission lines produced by excited elements?
Bohr addressed these questions using a seemingly simple assumption: what if some aspects of atomic structure, such as electron orbits and energies, could only take on certain values?
Quantization and photons
By the early 1900s, scientists were aware that some phenomena occurred in a discrete, as opposed to continuous, manner. Physicists Max Planck and Albert Einstein had recently theorized that electromagnetic radiation not only behaves like a wave, but also sometimes like particles called photons. Planck studied the electromagnetic radiation emitted by heated objects, and he proposed that the emitted electromagnetic radiation was "quantized" since the energy of light could only have values given by the following equation: , where is a positive integer, is Planck’s constant——and is the frequency of the light, which has units of .
As a consequence, the emitted electromagnetic radiation must have energies that are multiples of . Einstein used Planck's results to explain why a minimum frequency of light was required to eject electrons from a metal surface in the photoelectric effect.
When something is quantized, it means that only specific values are allowed, such as when playing a piano. Since each key of a piano is tuned to a specific note, only a certain set of notes—which correspond to frequencies of sound waves—can be produced. As long as your piano is properly tuned, you can play an F or F sharp, but you can't play the note that is halfway between an F and F sharp.
Atomic line spectra
Atomic line spectra are another example of quantization. When an element or ion is heated by a flame or excited by electric current, the excited atoms emit light of a characteristic color. The emitted light can be refracted by a prism, producing spectra with a distinctive striped appearance due to the emission of certain wavelengths of light.
For the relatively simple case of the hydrogen atom, the wavelengths of some emission lines could even be fitted to mathematical equations. The equations did not explain why the hydrogen atom emitted those particular wavelengths of light, however. Prior to Bohr's model of the hydrogen atom, scientists were unclear of the reason behind the quantization of atomic emission spectra.
Bohr's model of the hydrogen atom: quantization of electronic structure
Bohr’s model of the hydrogen atom started from the planetary model, but he added one assumption regarding the electrons. What if the electronic structure of the atom was quantized? Bohr suggested that perhaps the electrons could only orbit the nucleus in specific orbits or shells with a fixed radius. Only shells with a radius given by the equation below would be allowed, and the electron could not exist in between these shells. Mathematically, we could write the allowed values of the atomic radius as , where is a positive integer, and is the Bohr radius, the smallest allowed radius for hydrogen.
He found that has the value
By keeping the electrons in circular, quantized orbits around the positively-charged nucleus, Bohr was able to calculate the energy of an electron in the th energy level of hydrogen: , where the lowest possible energy or ground state energy of a hydrogen electron——is .
Note that the energy is always going to be a negative number, and the ground state, , has the most negative value. This is because the energy of an electron in orbit is relative to the energy of an electron that has been completely separated from its nucleus, , which is defined to have an energy of . Since an electron in orbit around the nucleus is more stable than an electron that is infinitely far away from its nucleus, the energy of an electron in orbit is always negative.
Absorption and emission
The energy level diagram showing transitions for Balmer series, which has the n=2 energy level as the ground state.
Bohr could now precisely describe the processes of absorption and emission in terms of electronic structure. According to Bohr's model, an electron would absorb energy in the form of photons to get excited to a higher energy level as long as the photon's energy was equal to the energy difference between the initial and final energy levels. After jumping to the higher energy level—also called the excited state—the excited electron would be in a less stable position, so it would quickly emit a photon to relax back to a lower, more stable energy level.
The energy levels and transitions between them can be illustrated using an energy level diagram, such as the example above showing electrons relaxing back to the level of hydrogen. The energy of the emitted photon is equal to the difference in energy between the two energy levels for a particular transition. The energy difference between energy levels and can be calculated using the equation for from the previous section:
Since we also know the relationship between the energy of a photon and its frequency from Planck's equation, we can solve for the frequency of the emitted photon:
We can also find the equation for the wavelength of the emitted electromagnetic radiation using the relationship between the speed of light , frequency , and wavelength :
Thus, we can see that the frequency—and wavelength—of the emitted photon depends on the energies of the initial and final shells of an electron in hydrogen.
What have we learned since Bohr proposed his model of hydrogen?
The Bohr model worked beautifully for explaining the hydrogen atom and other single electron systems such as . Unfortunately, it did not do as well when applied to the spectra of more complex atoms. Furthermore, the Bohr model had no way of explaining why some lines are more intense than others or why some spectral lines split into multiple lines in the presence of a magnetic field—the Zeeman effect.
In the following decades, work by scientists such as Erwin Schrödinger showed that electrons can be thought of as behaving like waves and behaving as particles. This means that it is not possible to know both a given electron’s position in space and its velocity at the same time, a concept that is more precisely stated in Heisenberg's uncertainty principle. The uncertainty principle contradicts Bohr’s idea of electrons existing in specific orbits with a known velocity and radius. Instead, we can only calculate probabilities of finding electrons in a particular region of space around the nucleus.
The modern quantum mechanical model may sound like a huge leap from the Bohr model, but the key idea is the same: classical physics is not sufficient to explain all phenomena on an atomic level. Bohr was the first to recognize this by incorporating the idea of quantization into the electronic structure of the hydrogen atom, and he was able to thereby explain the emission spectra of hydrogen as well as other one-electron systems.
Want to join the conversation?
- what is quantum(48 votes)
- A quantum is the minimum amount of any physical entity involved in an interaction, so the smallest unit that cannot be a fraction.(137 votes)
- What does ΔE stand for?(16 votes)
- *The triangle stands for Delta, which also means a change in, in your case, this means a change in energy.*(9 votes)
- what is the relationship between energy of light emitted and the periodic table ?(12 votes)
- Its a really good question. Here is my answer, but I would encourage you to explore this and similar questions further..
OK: I would say that the periodic table tells us about the number of protons in an element; and, therefore the number of electrons too.
Now, the energy of the photon emitted from any element does not depend on the number of electrons in the atom. The value of the energies of photons does depend on the available energy levels in the atom. Hydrogen, for example, although the simplest atom, has a whole range of photon energies that it emits. This is because the electron can exist in many energy levels... as it switches from one energy level to another, then it emits / absorbs photons.
We can, however, say that the more electrons there are in an atom, the greater the variety of photon energies there will be so this may be a link worth exploring
I hope that makes sense ok.
As I say, you are asking a great question.... looking for relationships in a meaningful way. I would encourage you to explore further.... maybe compare the number of different energies emitted by an element with its position in the periodic table, or the maximum / minimum energies emitted by the element vs position
Well done and keep up the good work.(30 votes)
- I don't get why the electron that is at an infinite distance away from the nucleus has the energy 0 eV; because, an electron has the lowest energy when its in the first orbital, and for an electron to move up an orbital it has to absorb energy, which would mean the higher up an electron is the more energy it has. So if an electron is infinitely far away(I am assuming infinity in this context would mean a large distance relative to the size of an atom) it must have a lot of energy. Right?
Thanks very much!(2 votes)
- you are right!
but what you need to remember now, is that the energy at infinity is DEFINED as being zero. Your next queston might be 'why?' :)
but, knowing that, does it now make sense that nearer to the nucleus, the energy is minus??(33 votes)
- Hi, great article. I was wondering, in the image representing the emission spectrum of sodium and the emission spectrum of the sun, how does this show that there is sodium in the sun's atmosphere? If both pictures are of emission spectra, and there is in fact sodium in the sun's atmosphere, wouldn't it be the case that those two dark lines are filled in on the sun's spectrum. The text below the image states that the bottom image is the sun's emission spectrum. Wouldn't that comparison only make sense if the top image was of sodium's emission spectrum, and the bottom was of the sun's absorbance spectrum?
- Sodium in the atmosphere of the Sun does emit radiation indeed. However, after photon from the Sun has been absorbed by sodium it loses all information related to from where it came and where it goes. So re emittion occurs in the random direction, resulting in much lower brightness compared to the intensity of the all other photos that move straight to us.(6 votes)
- Actually, i have heard that neutrons and protons are made up of quarks (6 kinds? up down ......)
Is it true? and how does the scientists found that out?(13 votes)
- yes, protons are made of 2 up and 1 down quarks whereas neutrons are made of 2 down and 1 up quarks . hope this helps.(2 votes)
- Bohr said that electron does not radiate or absorb energy as long as it is in the same circular orbit. But according to the classical laws of electrodynamics it radiates energy. What is the reason for not radiating or absorbing energy?(10 votes)
- Bohr did not answer to it.But Schrodinger's explanation regarding dual nature and then equating hV=mvr explains why the atomic orbitals are quantised(3 votes)
- why does'nt the bohr's atomic model work for those atoms that have more than one electron ?(5 votes)
- As far as i know, the answer is that its just too complicated.
With one electron and one proton you can figure out (with some difficulty) how they interact with one another because you have one centripetal force acting in the same 'direction' and analyse-able using classical circular motion etc.
But with two electrons, now you have three forces; not just centripetal but also electron to electron. You can imagine in the classical view, how complex the change on force would be between the electrons and also the nucleus. It may be tht some one has figured a way of doing it or approximating to it, but, as far as I know this is the reason bohr model is only used for hydrogen.(11 votes)
- What exactly does wavelength transition mean? What would be the logic to calculate the longest and shortest wavelength transitions of an element, say Hydrogen?(4 votes)
- Is Bohr's Model the most accurate model of atomic structure?(2 votes)
- No, it is not. The quantum description of the electron orbitals is the best description we have.(10 votes)