Electrochemistry, thermodynamics, and equilibrium
Free energy and cell potential
- [Voiceover] When you're dealing with a voltaic cell, it's important to relate the potential of the cell to the free energy of the redox reaction. And here's the equation that relates free energy to the cell potential. So delta G, delta G is the change in free energy. And we know for a spontaneous reaction delta G is negative. So let me go ahead and write that down here. So delta G is negative for our spontaneous redox reaction that we have in our voltaic cell. And we're going to calculate the value for delta G at the end of this video. E over here, this represents our cell potential, or our cell voltage. And this is easy to measure. Just hook up a voltmeter and for this cell the cell potential is positive 1.10 volts. So very easy to measure the voltage associated with a voltaic cell. Next, the n, the n represents the moles of electrons that are transferred in the redox reaction. In this example we're talking about two moles of electrons are transferred in our redox reaction. And finally, let's talk about F, which represents Faraday's constant. And Faraday's constant is the magnitude of charge that's carried by one mole of electrons. So we can calculate Faraday's constant, let's go ahead and do that up here. So one electron has a charge of 1.6 times 10 to the negative 19 coulombs. Coulombs is the unit for charge. So let's go ahead and write that. 1.6, actually it's 1.602, times 10 to the negative 19 coulombs, for every one electron. So one electron has that charge. If we want to find the magnitude of charge carried by one mole of electrons, we would need to multiply by Avogadro's number. So if we multiply by Avogadro's number, which we know is 6.022 times 10 to the 23rd. That's how many electrons there are in one mole of electrons. So that's how many electrons in one mole of electrons. If you multiply these out, you're gonna end up with charge per one mole of electrons. Let's get out the calculator and let's find Faraday's constant. So we have 1.602 times 10 to the negative 19. And we're going to multiply that by Avogadro's number, 6.022 times 10 to the 23rd. And we get 96,472, so this is 96,472. The units would be, this is coulombs per mole of electrons. So coulombs per mole. And if you do a more careful calculation, you'll get 96,485 coulombs per mole. And so sometimes you'll see textbooks use this number for different calculations. Most of the time you can just round this to 96,500. So 96,500 coulombs per mole. And that's good enough for almost all the calculations that you will do. So that explains each term of our equation here. So this cell potential that we talked about, 1.10 volts, this is actually the standard cell potential. Which is the voltage measured when the cell operates under standard conditions. Which is defined as, all of your solids are in pure form and that's the case for us here, because we're dealing with zinc metal. So that's a solid in its pure form. And copper metal, a solid in its pure form. Also defined as the solutions are at one molar concentrations. We have a one molar concentration solution of zinc sulfate, which gives us one molar concentration of zinc two plus ions in solution. And a one molar concentration of copper sulfate, which gives us one molar concentration of copper two plus ions in solution. And our temperature is 25 degrees. So this is 25 degrees C. So if those are your conditions and you hook up a voltmeter, this is the voltage that you will get. So we can actually modify the equation that we've talked about by adding in a superscript here. So we could write E zero instead of just E. And E zero is our standard cell potential. It just means that everything is under the conditions, under standard conditions. And then this would be delta G zero. So that's delta G zero now, the standard change in free energy. So let's go ahead and solve for delta G zero. We already know it's gonna be negative, because this is a spontaneous redox reaction. But let's go ahead and plug in everything. So let's get a little bit more room down here. And let's plug in our numbers. So we're trying to solve for delta G zero, the standard change in free energy. So we have a negative sign here, I'll talk about what that means a little bit later. So next we have n. Remember what n represented here. So n is the moles of electrons that are transferred in our redox reaction. Which would be two. So this would be two moles of electrons. And we put these in parentheses here. Next we have Faraday's constant, F. And so we've already seen that we can use 96,500 coulombs per mole for Faraday's constant. So this is 96,500 coulombs per mole. Next we plug in the value for our standard cell potential. So E zero is 1.10 volts for this voltaic cell. And, when you're thinking about units, so a volt is how many joules per coulomb? So instead of plugging in volts here, we're gonna plug in joules over coulombs so our units will work out properly. So this is positive 1.10 jules per coulomb. Let's do this math. So let's look our units first and let's see what cancels out here. So our moles cancels out. Our charge, coulombs, cancels out to give us joules for our answer. So let's go ahead and calculate how many joules. Let's do the calculations, we have two times 96,500. And then we're gonna multiply that by 1.10. So that would give us, this would give us, 212,300 joules. So remember this was in joules. And let's go ahead and convert that to kilojoules. So 212,000 joules would be 212 kilojoules. And remember we have a negative sign here. So don't forget about this negative sign. This would be negative 212 kilojoules for our value for delta G zero. So the standard change in free energy for this voltaic cell is negative 212 kilojoules. And we already know that when delta G is negative, that's a spontaneous reaction. So this is a spontaneous redox reaction here. Notice that delta G zero and E zero have opposite signs. We had a positive sign for our voltage and we ended up with a negative sign for delta G. And that's why we have this negative in our equation here. So a spontaneous reaction in a voltaic cell has a positive cell potential, so a positive value for the voltage, but a negative change in free energy, because that indicates a spontaneous reaction.