Main content
Chemistry library
Course: Chemistry library > Unit 14
Lesson 2: Titrations- Acid–base titrations
- Worked example: Determining solute concentration by acid–base titration
- Titration of a strong acid with a strong base
- Titration of a strong acid with a strong base (continued)
- Titration of a weak acid with a strong base
- Titration of a weak acid with a strong base (continued)
- Titration of a weak base with a strong acid
- Titration of a weak base with a strong acid (continued)
- 2015 AP Chemistry free response 3b
- 2015 AP Chemistry free response 3c
- 2015 AP Chemistry free response 3d
- 2015 AP Chemistry free response 3e
- 2015 AP Chemistry free response 3f
- Titration curves and acid-base indicators
- Redox titrations
- Introduction to titration
© 2023 Khan AcademyTerms of usePrivacy PolicyCookie Notice
2015 AP Chemistry free response 3c
Choosing an indicator for a titration. From 2015 AP Chemistry free response 3c.
Want to join the conversation?
- Why exactly do you choose the indicator with the pKa value as close as possible to the pH of the equivalence point?(14 votes)
- You can't use the Henderson–Hasselbalch equation since you will get a division by 0 (there's 0 concentration of acid, and this isn't a buffer). I found a much better explanation here (scroll to "The pH range of indicators"): https://www.chemguide.co.uk/physical/acidbaseeqia/indicators.html(6 votes)
Video transcript
- [Voiceover] The pH at
the equivalence point of the titration is measured to be 2.54. Which of the following indicators would be the best choice for determining the end point of the titration? Justify your answer. Well let's just remind ourselves, the endpoint of the titration is when the indicator changes color, and because that's our
signal, our visual signal, it's saying, "Hey, we must've
hit the equivalence point," you want the pKa of your indicator to be as close as possible to the pH at the equivalence point. If the pH at the
equivalence point is 2.54, well which of these indicators
have the closes pKa to that? Well we see thymol blue has
it at two right over here, so we would choose to use thymol blue, thymol blue, because its pKa closest to pH at equivalence point. Equivalence, equivalence point. There you go.