- [Voiceover] Ionic bonds are the bonds that hold together ionic compounds. So basically it's what holds
together cations and anions. An example of a compound that's held together with ionic bonds is sodium chloride, also
known as table salt. So here we have a close-up picture of some really nice
crystals of sodium chloride. And this is something that
you could try at home. You can take any table
salt that you might have, dissolve it up in some water, and then let that water slowly evaporate. And if you're lucky, you might get some beautiful symmetric crystals like these. For me personally at least, growing crystals that look beautiful is one of the most fun
things about chemistry. You can see when we look at the close-up shapes of these crystals that they have some
very beautiful symmetry. That symmetry tells us a little bit about the structure of these compounds on a molecular level. If we zoom in on these crystals, we can imagine, actually
we don't have to imagine, you can look at these with
different kinds of instruments like x-ray crystallography, and you can look at the crystal lattice and get information about how the different ions are
arranged in the solids. So the way that the ions are arranged determines a lot of things about the properties of these compounds. So these ionic bonds and
how the ions are arranged tell us a lot about the
solubility of the compound. Solubility. And other properties like
melting or boiling points. And it even can be related back to things like how hard a particular ionic solid is. So the ionic bonds here,
in the sodium chloride, are the ones that hold together our sodium ions and our chloride ions. So our sodium plus and our chloride minus. And the strength of an ionic bond is related to the electrostatic force. The electrostatic force between them. And I'm going to abbreviate
the electrostatic force as F subscript e. So this is the force
between two charged species. And it's equal to some constant k... Times the two charges that are interacting divided by the distance between
the two charges squared. So here, q1 and q2 are the charges, and in the case of sodium
chloride for example, q1 and q2 would be... q1 might be one plus, from our sodium ion, and q2 might be one minus,
from our chloride ion. And we could also just switch those two, we could say chloride
is q1 and sodium is q2, and that wouldn't change what
we get from this equation. And then r2 here, is the
distance between the ions, and we usually approximate it as saying it's the sum of the ionic radii... for the two ions we're looking at. So we can use Coulomb's law here to explain some properties
that are related to the strengths of ionic bonds. And so the example we're
gonna go through today is going to be that of melting point. So we're gonna look at
some melting point trends and try to relate them to the different variables in Coulomb's law. So the first thing we'll look at, the first two compounds we'll compare are sodium fluoride... and magnesium oxide. Sodium fluoride has a melting
point of 993 degrees Celsius, and magnesium oxide has a melting point of 2852 degrees Celsius. The other information we know
about these two compounds, if you look up the ionic radii, it turns out that sodium fluoride, the distance between the ions is about the same as magnesium oxide. They're not exactly the same,
but they're pretty close, so if we were to say that r is approximately the same for these two, then we can explain the difference in melting points using the charges. Since melting point is a measure of, basically how much energy do you need to add to these compounds
to break apart your ions, we would expect melting point to go up, to increase, as Fe increases. As the force between the ions increases, we would expect to have to add more energy to break those ions apart. And we can see that in our first example. Magnesium oxide, if we look
at the charges on the ions, magnesium is two plus,
and oxide is two minus. In sodium fluoride, sodium is one plus, and fluoride is one minus. So we would expect, assuming
that r is about the same, this q1 times q2 is four times bigger in magnesium oxide versus sodium fluoride. So q1 and q2, the product of q1 and q2... is higher for magnesium oxide, and that's why we would expect the melting point to be higher. We can also look at sodium
chloride versus sodium fluoride. And in this case, let's look at, well, I don't know, maybe
this is kind of artificial, the boiling point, the melting point, sorry, the melting
point of sodium chloride is 801 degrees Celsius... and the melting point
of sodium fluoride is, like we said early, 993 degrees Celsius. And so this time, the charges
are the same on our ions, our q1 and q2 is one plus for
the sodium in both compounds, and one minus for the
chloride and the fluoride. So q1 times q2 didn't change
for these two compounds, but since we changed the anion
from fluoride to chloride, we increased r here, and increasing r in the denominator makes the electrostatic force goes down. Another way we could put it
is that since r decreases, as we go from sodium
chloride to sodium fluoride, the melting point goes up. So in each of these pairs, the compound that has
the higher melting point is the one that also... has the higher electrostatic forces, and that's either because
the charges are higher, q1 and q2 are higher, or because the distance
between the ions went down. So these are some examples
for how we can relate the properties of ionic compounds to the electrostatic
force using Coulomb's law between the cation and the anion.